Suleiman Gwaram Nura, Ikmal Hisham Nurul Azimah, Khaledi Hamid, Mohd Ali Hapipah
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 11;67(Pt 1):m58. doi: 10.1107/S1600536810050889.
In the title compound, [Cu(NCS)(2)(C(13)H(19)N(3)O)], the Cu(II) ion is five-coordinated by the N,N',N''-tridentate Schiff base and the N atoms of two isothio-cyanate ligands in a square-pyramidal geometry. In the crystal, C-H⋯N, C-H⋯O and C-H⋯S inter-actions link adjacent mol-ecules into layers parallel to the ac plane. A weak inter-molecular π-π inter-action occurs between the aromatic rings with a centroid-centroid distance of 3.9412 (9) Å.
在标题化合物[Cu(NCS)₂(C₁₃H₁₉N₃O)]中，Cu(II)离子由N,N',N''-三齿席夫碱以及两个异硫氰酸酯配体的N原子以四方锥几何构型进行五配位。在晶体中，C—H⋯N、C—H⋯O和C—H⋯S相互作用将相邻分子连接成平行于ac平面的层。芳香环之间发生弱的分子间π-π相互作用，质心间距为3.9412 (9) Å。
