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Bis(tetra-butyl-ammonium) bis-(3,4,5-trioxocyclo-pent-1-ene-1,2-dithiol-ato-κS,S')cadmate(II) 0.25-hydrate.

作者信息

Chen Hong-Yu, Xia Guang-Ming, Zhang Zhen-Wei, Li Ping

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 4;67(Pt 1):m12-3. doi: 10.1107/S1600536810049913.

DOI:10.1107/S1600536810049913
PMID:21522531
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3050421/
Abstract

The title compound, (C(16)H(36)N)(2)[Cd(C(5)O(3)S(2))(2)]·0.25H(2)O, contains two disordered tetra-butyl-ammonium cations, a complex Cd(C(5)O(3)S(2))(2) anion and a 0.25-hydrate water. The anion is composed of a bidentate coordinated 3,4,5-trioxocyclo-pent-1-ene-1,2-dithiol-ate (dtcroc) group forming a distorted tetra-hedral configuration around the Cd(II) ion. The dihedral angle between the least-squares planes of the ten-atom sulfur-substituted croconate groups in the anion is 84.10 (8)°. The crystal packing is stabilized by weak C-H⋯O and C-H⋯S cation-anion hydrogen-bond inter-actions. In each of the two cations one butyl group is disordered over two positions in the ratios 0.589 (11):0.411 (11) and 0.796 (12):0.204 (12).

摘要

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本文引用的文献

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Synthesis, crystal structure and properties of the semiconducting salts (TTF)2[Ni(dtcr)2] and (ET)2[Ni(dtcr)2] based on [Ni(dtcr)2] dianions (dtcr = dithiocroconate).基于[Ni(dtcr)2]二价阴离子（dtcr = 二硫代巴豆酸根）的半导体盐(TTF)2[Ni(dtcr)2]和(ET)2[Ni(dtcr)2]的合成、晶体结构及性质
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