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Diaqua-bis-(2-oxo-2H-chromene-3-carboxyl-ato-κO,O)cadmium.

作者信息

Cui Yue, Gao Qian, Wang Huan-Huan, Wang Lin, Xie Ya-Bo

机构信息

College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 24;67(Pt 1):m126. doi: 10.1107/S1600536810053523.

Abstract

In the title mononuclear cadmium complex, [Cd(C(10)H(5)O(4))(2)(H(2)O)(2)], the Cd(II) atom, located on a crystallographic inversion center, exhibits a slightly distorted octa-hedral geometry and is six-coordinated by two O atoms from water mol-ecules in the axial positions and four O atoms from two deprotonated coumarin-3-carb-oxy-lic acid ligands in the equatorial plane. Angles around the Cd(II) atom vary between 81.00 (5) and 99.00 (0)°. The Cd-O bond lengths vary between 2.1961 (13) and 2.3360 (13) Å. O-H⋯O hydrogen bonds between the H atoms of coordinated water mol-ecules and the O atoms of carboxyl-ate groups link the complex mol-ecules into layers parallel to the ab plane.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8d2f/3050216/5b9d1aaf7343/e-67-0m126-fig1.jpg

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