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[(1,2,5,6-η)-环辛-1,5-二烯]双(4-甲基苯基)铂(II)

[(1,2,5,6-η)-Cyclo-octa-1,5-diene]bis-(4-methyl-phen-yl)platinum(II).

作者信息

Wang Zhi-Wei, Liu Ran, Liu Hong-Yu, Wan Chong-Qing

机构信息

Department of Chemistry, Capital Normal University, Beijing 100048, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 4;67(Pt 1):m37. doi: 10.1107/S1600536810049664.

Abstract

In the mononuclear title complex, [Pt(C(7)H(7))(2)(C(8)H(12))], the Pt(II) ion exhibits a square-planar coordination geometry defined by two methyl-phenyl ligands and the mid-points of the two π-coordinated double bonds of cyclo-octa-1,5-diene. The two methyl-phenyl groups have a cis relationship with a C-Pt-C bond angle of 88.54 (18)° and a dihedral angle between the mean planes of the benzene rings of 83.87 (1)°. Each complex mol-ecule links to four symmetry-related ones through inter-molecular C-H⋯π inter-actions, forming a layer almost parallel to the bc plane.

摘要

在单核标题配合物[Pt(C₇H₇)₂(C₈H₁₂)]中,Pt(II)离子呈现出由两个甲基苯基配体以及环辛-1,5-二烯的两个π配位双键的中点所定义的平面正方形配位几何构型。两个甲基苯基基团呈顺式关系,C-Pt-C键角为88.54 (18)°,苯环平均平面之间的二面角为83.87 (1)°。每个配合物分子通过分子间C-H⋯π相互作用与四个对称相关的分子相连,形成一个几乎平行于bc平面的层。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35b0/3050351/77838de985cd/e-67-00m37-fig1.jpg

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