2,4,6-三甲基吡啶磷酸二氢盐
2,4,6-Trimethyl-pyridinium dihydrogen phosphate.
作者信息
Cai Hong-Ling, Dai Jing
机构信息
Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 18;67(Pt 1):o72. doi: 10.1107/S1600536810050646.
In the title compound, C(8)H(9)N(+)·H(2)PO(4) (-), both the cation and anion have crystallographically imposed mirror symmetry (all atoms apart from one O atom lie on the mirror plane). In the crystal, anions and cations are linked by O-H⋯O and π-π stacking inter-actions [centroid-centroid distance = 3.4574 (6) Å], forming chains parallel to the b axis. Adjacent chains are further connected by N-H⋯O hydrogen bonds into a two-dimensional network.
在标题化合物C₈H₉N⁺·H₂PO₄⁻中，阳离子和阴离子在晶体学上均具有镜像对称性（除一个O原子外的所有原子都位于镜面上）。在晶体中，阴离子和阳离子通过O—H⋯O和π–π堆积相互作用相连[质心-质心距离 = 3.4574 (6) Å]，形成平行于b轴的链。相邻的链通过N—H⋯O氢键进一步连接成二维网络。
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