Wang Ming-Liang, Dong Bao-Li, Li Yong-Hua
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 11;67(Pt 1):o94. doi: 10.1107/S160053681005018X.
In the title compound, C(25)H(20)N(2)O, the pyrazoline ring is nearly planar [maximum atomic deviation = 0.0254 (17) Å]; but the anthracene ring system is distorted from a coplanar structure [maximum atomic deviation = 0.181 (3) Å], the dihedral angle between the outer benzene rings being 10.68 (13)°. The pyrazoline ring is almost perpendicular to the mean plane of the anthracene ring system [dihedral angle = 76.94 (8)°], but nearly coplanar with the phenyl ring [dihedral angle = 1.63 (7)°]. π-π stacking is observed between parallel benzene rings of adjacent anthracene units, the face-to-face distance being 3.27 (3) Å. Weak intra-molecular C-H⋯N hydrogen bonding also occurs.