氯亚硝基 - [内消旋 - 5,10,15,20 - 四 - （对甲苯基）卟啉合 - κN，N'，N''，N''']锇（II）四氢呋喃四溶剂化物
Chloridonitros-yl[meso-5,10,15,20-tetra-kis-(p-tol-yl)porphyrinato-κN,N',N'',N''']osmium(II) tetra-hydro-furan tetra-solvate.
作者信息
Chen Li, Xu Nan, Powell Douglas R, Richter-Addo George B
机构信息
Department of Chemistry and Biochemistry, University of Oklahoma, 101 Stephenson Parkway, Norman, OK 73019-5251, USA.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 22;67(Pt 2):m224. doi: 10.1107/S1600536811001401.
The title compound, [OsCl(NO)(C(48)H(36)N(4))]·4C(4)H(8)O, is a six-coordinate osmium(II) porphyrin complex with nitrosyl (NO) and chloride (Cl) ligands trans to each other in an octa-hedral geometry. The metal complex lies on a fourfold rotation axis that passes through the Os, N, O and Cl atoms. The NO and Cl ligands are disordered in an 0.511 (12):0.486 (12) ratio.
标题化合物[OsCl(NO)(C₄₈H₃₆N₄)]·4C₄H₈O是一种六配位的锇（II）卟啉配合物，在八面体几何构型中，亚硝酰基（NO）和氯（Cl）配体彼此反位。金属配合物位于一条通过Os、N、O和Cl原子的四重旋转轴上。NO和Cl配体以0.511 (12):0.486 (12)的比例无序排列。
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