双{苄基 3-[(1H-吲哚-3-基)亚甲基]二硫代氨基甲酸盐-κN,S}钯(II)吡啶二溶剂合物
Bis{benzyl 3-[(1H-indol-3-yl)methyl-idene]dithio-carbazato-κN,S}palladium(II) pyridine disolvate.
作者信息
Khaledi Hamid, Mohd Ali Hapipah
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 22;67(Pt 2):m230. doi: 10.1107/S1600536811001991.
The Pd(II) ion in the title compound, [Pd(C(17)H(14)N(3)S(2))(2)]·2C(5)H(5)N, is located on an inversion center and is four-coordinated by two of the deprotonated N,S-bidentate Schiff base ligands in a square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 71.12 (9)°. The indole NH groups are bonded to the pyridine solvent mol-ecules via an N-H⋯N inter-action. The crystal structure is consolidated by inter-molecular C-H⋯S inter-actions.
标题化合物[Pd(C₁₇H₁₄N₃S₂)₂]·2C₅H₅N中的Pd(II)离子位于一个对称中心上，由两个去质子化的N,S-双齿席夫碱配体以平面正方形几何构型进行四配位。配体内芳香环平面之间的二面角为71.12 (9)°。吲哚NH基团通过N—H⋯N相互作用与吡啶溶剂分子相连。晶体结构通过分子间C—H⋯S相互作用得以巩固。
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