双[苄基N'-(1H-吲哚-3-基亚甲基)肼基二硫代甲酸根合-κN',S]镍(II) N,N-二甲基甲酰胺溶剂化物
Bis[benzyl N'-(1H-indol-3-ylmethyl-ene)hydrazinecarbodithio-ato-κN',S]nickel(II) N,N-dimethyl-formamide disolvate.
作者信息
Khaledi Hamid, Mohd Ali Hapipah, Ng Seik Weng
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 26;64(Pt 12):m1615. doi: 10.1107/S1600536808038580.
Abstract
In the title compound, [Ni(C(17)H(14)N(3)S(2))(2)]·2C(3)H(7)NO, the Ni atom (site symmetry ) is N,S-chelated by two deprotonated Schiff base anions in a distorted square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 86.37 (13)°. In the crystal structure, an N-H⋯O hydrogen bond links the complex to the dimethyl-formamide solvent mol-ecule.
摘要
在标题化合物[Ni(C₁₇H₁₄N₃S₂)₂]·2C₃H₇NO中，Ni原子（位点对称性 ）被两个去质子化的席夫碱阴离子以扭曲的平面正方形几何构型进行N、S螯合。配体内芳香环平面之间的二面角为86.37 (13)°。在晶体结构中，一个N—H⋯O氢键将配合物与二甲基甲酰胺溶剂分子相连。
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