双[2-(环戊基亚氨基甲基)-4-硝基苯酚根-κN,O]钴(II)
Bis[2-(cyclo-pentyl-imino-meth-yl)-4-nitro-phenolato-κN,O]cobalt(II).
作者信息
Xu Mai, Wei Yi-Jun, Wang Feng-Wu
机构信息
Department of Chemistry, Huainan Normal College, Huainan 232001, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 22;67(Pt 2):m245. doi: 10.1107/S1600536811002194.
In the title compound, [Co(C(12)H(13)N(2)O(3))(2)], the Co(II) ion is situated on a twofold rotation axis and is coordinated by two N and two O atoms from two symmetry-related Schiff base 2-(cyclo-pentyl-imino-meth-yl)-4-nitro-phenolate ligands (L) in a distorted tetra-hedral geometry. The cyclo-pentyl ring in L is disordered over two conformations in a 0.640 (19):0.360 (19) ratio.
在标题化合物[Co(C₁₂H₁₃N₂O₃)₂]中，Co(II)离子位于一个二重旋转轴上，由来自两个对称相关的席夫碱2-(环戊基亚氨基甲基)-4-硝基苯酚配体(L)的两个N原子和两个O原子以扭曲的四面体几何构型配位。配体L中的环戊基环在两种构象上无序，比例为0.640(19):0.360(19)。
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