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双{2,4 - 二溴 - 6 - [(2 - 苯基 - 乙基)亚氨基 - 甲基]苯酚根合 - κN,O}钴(II)

Bis{2,4-dibromo-6-[(2-phenyl-eth-yl)imino-meth-yl]phenolato-κN,O}cobalt(II).

作者信息

Yin Yanli, Wang Jinrong, Zhao Yongliang, Huang Liang

机构信息

College of Biological Engineering, Henan University of Technology, Zhengzhou, Henan 450001, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1642. doi: 10.1107/S160053681104459X. Epub 2011 Oct 29.

DOI:10.1107/S160053681104459X
PMID:22219863
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3247558/
Abstract

In the title complex, [Co(C(15)H(12)Br(2)NO)(2)], the Co(II) atom is four-coordinated by two N,O-bidentate chelate Schiff base ligands, displaying a flattened tetra-hedral coordination environment. The Co(II) atom occupies a special position on a twofold rotation axis. In the crystal, mol-ecules are linked via weak C-H⋯Br inter-actions.

摘要

在标题配合物[Co(C₁₅H₁₂Br₂NO)₂]中，Co(II)原子由两个N,O-双齿螯合席夫碱配体四配位，呈现出扁平的四面体配位环境。Co(II)原子占据一个二重旋转轴上的特殊位置。在晶体中，分子通过弱的C-H⋯Br相互作用相连。

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本文引用的文献

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Bis[2,4-dibromo-6-(n-propyl-imino-methyl)phenolato-κN,O]cobalt(II).双[2,4-二溴-6-(正丙基亚氨基甲基)苯酚根-κN,O]钴(II)
Acta Crystallogr Sect E Struct Rep Online. 2010 Aug 18;66(Pt 9):m1123. doi: 10.1107/S1600536810032162.
2
Bis{2-[(E)-benzyl-imino-meth-yl]-4,6-dibromo-phenolato-κN,O}cobalt(II).双{2-[(E)-苄基亚氨基甲基]-4,6-二溴苯酚根-κN,O}钴(II)
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 15;64(Pt 11):m1394. doi: 10.1107/S1600536808032303.
3
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Vitamin B12: unique metalorganic compounds and the most complex vitamins.维生素 B12：独特的金属有机化合物和最复杂的维生素。
Molecules. 2010 Apr 30;15(5):3228-59. doi: 10.3390/molecules15053228.
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A short history of SHELX.SHELX简史。
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