Lemmerer Andreas, Michael Joseph P
Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand, Johannesburg, PO Wits 2050, South Africa.
Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 15;67(Pt 2):o394. doi: 10.1107/S1600536811001048.
In the racemic title compound, C(14)H(16)N(2), the aromatic ring component of the amino-indoline system occupies the endo cavity of the norbornane component. The aromatic ring lies at an angle of 74.12 (5)° to the plane defined by the four C atoms that comprises the rigid part of the boat-shaped six-membered ring of the norbornane unit. Pairs of mol-ecules assemble in the crystal structure, forming centrosymmetric hydrogen-bonded dimers via pairs of N-H⋯N hydrogen bonds through the syn H atom of the amine group.
在消旋标题化合物C₁₄H₁₆N₂中，氨基吲哚啉体系的芳环部分占据了降冰片烷部分的内型空腔。芳环与由四个C原子所定义的平面呈74.12 (5)°的夹角，这四个C原子构成了降冰片烷单元船型六元环的刚性部分。分子对在晶体结构中聚集，通过胺基的顺式H原子经由N—H⋯N氢键对形成中心对称的氢键二聚体。
