Li Qi, Xue Wei-Jian
Key Laboratory of Pesticides and Chemical Biology of the Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 15;67(Pt 2):o400. doi: 10.1107/S1600536811001206.
The title compound, C(8)H(8)Br(2)O(2), was synthesized from the hydrolysis of 1,4-dibromo-2,3-bis-(bromo-meth-yl)benzene. One intra-molecular O-H⋯O and two intra-molecular C-H⋯Br inter-actions occur. In the crystal, mol-ecules are linked into a chain running parallel to [010]. Adjacent chains are linked into a two-dimensional layer by a combination of inter-molecular O-H⋯O hydrogen bonds and C-H⋯π inter-actions.
标题化合物C₈H₈Br₂O₂由1,4 - 二溴 - 2,3 - 双(溴甲基)苯水解合成。存在一个分子内O—H⋯O相互作用和两个分子内C—H⋯Br相互作用。在晶体中,分子连接成平行于[010]的链。相邻的链通过分子间O—H⋯O氢键和C—H⋯π相互作用的组合连接成二维层。