Department of Chemistry, Shantou University, Guangdong 515063, PR China.
Dalton Trans. 2011 Jun 7;40(21):5684-6. doi: 10.1039/c1dt10488h. Epub 2011 Apr 28.
The solvothermal in situ double cycloaddition reaction of 2-cyanopyrimidine, Cu(2)O and NaN(3) with aqueous ammonia additive generated a two dimensional copper(I) coordination polymer with 5-pyrimidyl-tetrazolate, 3,5-bispyrimidyl-1,2,4-triazolate and the cyano group as the ligands. This reaction can be tuned to yield two dimensional coordination polymers solely based on tetrazolate or 1,2,4-triazolate ligands.
溶剂热原位双环加成反应 2-氰基嘧啶、Cu(2)O 和 NaN(3)与氨水溶液添加剂生成二维铜（I）配位聚合物，具有 5-嘧啶基四唑、3,5-双嘧啶基-1,2,4-三唑和氰基作为配体。该反应可调节仅生成二维配位聚合物，配体仅基于四唑或 1,2,4-三唑。
