在转移氢化条件下，金（I）配合物催化的芳香醛的直接还原胺化反应。
Direct reductive amination of aromatic aldehydes catalyzed by gold(I) complex under transfer hydrogenation conditions.
机构信息
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.
出版信息
Chem Commun (Camb). 2011 Jun 21;47(23):6605-7. doi: 10.1039/c1cc11201e. Epub 2011 May 3.
PMID:21541418
Abstract
The direct reductive amination of aromatic aldehydes has been achieved with excellent isolated yields (89-96%) using readily accessible Ph(3)PAuCl/AgOTf catalyst along with ethyl Hantzsch ester as hydrogen source under mild reaction conditions.
摘要
使用易得的 Ph(3)PAuCl/AgOTf 催化剂和乙基 Hantzsch 酯作为氢源，在温和的反应条件下，实现了芳香醛的直接还原胺化，具有优异的分离收率（89-96%）。
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