State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.
Chem Commun (Camb). 2011 Jun 21;47(23):6605-7. doi: 10.1039/c1cc11201e. Epub 2011 May 3.
The direct reductive amination of aromatic aldehydes has been achieved with excellent isolated yields (89-96%) using readily accessible Ph(3)PAuCl/AgOTf catalyst along with ethyl Hantzsch ester as hydrogen source under mild reaction conditions.
使用易得的 Ph(3)PAuCl/AgOTf 催化剂和乙基 Hantzsch 酯作为氢源，在温和的反应条件下，实现了芳香醛的直接还原胺化，具有优异的分离收率（89-96%）。
