Department of Mechanical Engineering, Iowa State University, 2025 Black Engineering Building, Ames, Iowa 50011-2161, United States.
ACS Nano. 2011 Jun 28;5(6):4466-75. doi: 10.1021/nn2011442. Epub 2011 May 13.
An extremely focused optical field down to sub-10 nm in an apertureless near-field scanning optical microscope has been used widely in surface nanostructuring and structure characterization. The involved sub-10 nm near-field heating has not been characterized quantitatively due to the extremely small heating region. In this work, we present the first noncontact thermal probing of silicon under nanotip focused laser heating at a sub-10 nm scale. A more than 200 °C temperature rise is observed under an incident laser of 1.2 × 10(7) W/m(2), while the laser polarization is well aligned with the tip axis. To explore the mechanism of heating and thermal transport at sub-10 nm scale, a simulation is conducted on the enhanced optical field by the AFM tip. The high intensity of the optical field generated in this region results in nonlinear photon absorption. The optical field intensity under low polarization angles (∼10(14) W/m(2) within 1 nm region for 15° and 30°) exceeds the threshold for avalanche breakdown in silicon. The measured high-temperature rise is a combined effect of the low thermal conductivity due to ballistic thermal transport and the nonlinear photon absorption in the enhanced optical field. Quantitative analysis reveals that under the experimental conditions the temperature rise can be about 235 and 105 °C for 15° and 30° laser polarization angles, agreeing well with the measurement result. Evaluation of the thermal resistances of the tip-substrate system concludes that little heat in the substrate can be transferred to the tip because of the very large thermal contact resistance between them.
在无针近场扫描光学显微镜中,极其聚焦的光场可以达到亚 10nm,这在表面纳米结构和结构特征化方面得到了广泛应用。由于加热区域极小,涉及的亚 10nm 近场加热尚未得到定量描述。在这项工作中,我们首次在亚 10nm 尺度下展示了在纳米尖端聚焦激光加热下对硅的非接触热探测。在入射激光功率密度为 1.2×10(7) W/m(2)时,观察到超过 200°C 的温度升高,而激光偏振方向与尖端轴很好地对齐。为了探究亚 10nm 尺度下加热和热传输的机制,我们对 AFM 尖端增强的光场进行了模拟。在该区域产生的高强度光场导致非线性光吸收。在低偏振角下(对于 15°和 30°,在 1nm 区域内约为 10(14) W/m(2)),光场强度超过硅中雪崩击穿的阈值。所测量的高温升高是由于弹道热传输导致的低热导率和增强光场中的非线性光吸收的综合效应。定量分析表明,在实验条件下,对于 15°和 30°的激光偏振角,温度升高约为 235°C 和 105°C,与测量结果吻合较好。对尖端-衬底系统热阻的评估表明,由于它们之间的热接触电阻非常大,衬底中的热量几乎无法传递到尖端。