双[2-(3,4-二硫代苯基亚苯基)乙酸根合]双(2-甲基-1H-咪唑-κN)锌(II)
Bis[2-(3,4-disulfanylphen-yl)acetato]bis-(2-methyl-1H-imidazole-κN)zinc(II).
作者信息
Wang Qiang, Wang Li-Jun, Hou Jian
机构信息
Engineering Research Center for Clean Production of Textile Dyeing and Printing, Ministry of Education, Wuhan 430073, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 29;65(Pt 9):m1149. doi: 10.1107/S1600536809033893.
In the title mononuclear zinc(II) complex, [Zn(C(8)H(7)O(2)S(2))(2)(C(4)H(6)N(2))(2)], the Zn(II) atom, lying on a twofold axis, is coordinated by two O atoms from two 2-(3,4-disulfanylphen-yl)acetate anions and by two N atoms from 2-methyl-imidazole ligands in a distorted tetra-hdral coordination. The crystal structure is stabilized by inter-molecular C-H⋯O and N-H⋯O hydrogen bonds and π-π inter-actions with a centroid-centroid distance of 3.6136 (16) Å.
在标题单核锌（II）配合物[Zn(C₈H₇O₂S₂)₂(C₄H₆N₂)₂]中，位于二重轴上的Zn（II）原子由两个2-(3,4-二硫苯基)乙酸根阴离子的两个O原子和两个2-甲基咪唑配体的两个N原子以扭曲的四面体配位方式配位。晶体结构通过分子间的C-H⋯O和N-H⋯O氢键以及质心-质心距离为3.6136 (16) Å的π-π相互作用得以稳定。
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