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(Z)-6-[(5-氯-2-羟基-苯基)-氨亚甲基]-2-乙氧基-环己-2,4-二烯酮

(Z)-6-[(5-Chloro-2-hydroxy-phenyl)-aminomethyl-ene]-2-ethoxy-cyclo-hexa-2,4-dienone.

作者信息

Ozek Arzu, Albayrak Ciğdem, Büyükgüngör Orhan

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 15;65(Pt 9):o2153. doi: 10.1107/S1600536809031298.

DOI:10.1107/S1600536809031298
PMID:21577562
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2970131/
Abstract

The title compound, C(15)H(14)ClNO(3), exists as the keto-amine form in the crystal and two intra-molecular N-H⋯O hydrogen bonds are observed. The aromatic rings are oriented at a dihedral angle of 5.85 (8)°. In the crystal structure, inter-molecular O-H⋯O and C-H⋯O hydrogen bonds link the mol-ecules into chains. A π-π contact between the benzene rings [centroid-centroid distance = 3.6623 (10) Å] further stabilizes the structure.

摘要

标题化合物C(15)H(14)ClNO(3)在晶体中以酮胺形式存在,观察到两个分子内N-H⋯O氢键。芳环以5.85 (8)°的二面角取向。在晶体结构中,分子间的O-H⋯O和C-H⋯O氢键将分子连接成链。苯环之间的π-π接触[质心-质心距离 = 3.6623 (10) Å]进一步稳定了结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b0/2970131/82eeef287c50/e-65-o2153-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b0/2970131/8b367b3513cb/e-65-o2153-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b0/2970131/82eeef287c50/e-65-o2153-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b0/2970131/8b367b3513cb/e-65-o2153-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b0/2970131/82eeef287c50/e-65-o2153-fig2.jpg

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本文引用的文献

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A short history of SHELX.SHELX简史。
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Three (E)-2-[(bromophenyl)iminomethyl]-4-methoxyphenols.三种(E)-2-[(溴苯基)亚氨基甲基]-4-甲氧基苯酚。
Acta Crystallogr C. 2007 Mar;63(Pt 3):o177-80. doi: 10.1107/S0108270107003241. Epub 2007 Feb 17.
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Acta Crystallogr C. 2003 Oct;59(Pt 10):O601-2. doi: 10.1107/s0108270103018456. Epub 2003 Sep 23.