Adeel Muhammad, Ali Irshad, Langer Peter, Villinger Alexander
Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 19;65(Pt 9):o2176. doi: 10.1107/S1600536809031614.
In the title compound, C(17)H(17)ClO(4), the dihedral angle between the mean planes of the two benzene rings is 65.92 (5)°. The methyl ester group lies within the ring plane [deviations of O atoms from the plane = -0.051 (2) and 0.151 (2) Å] due to an intra-molecular O-H⋯O hydrogen bond. In the crystal, mol-ecules are held together by rather weak non-classical inter-molecular C-H⋯O hydrogen bonds, resulting in dimeric units about inversion centers, forming eight- and ten-membered ring systems as R(2) (2)(8) and R(2) (2)(10) motifs.
在标题化合物C₁₇H₁₇ClO₄中,两个苯环平均平面之间的二面角为65.92(5)°。由于分子内O—H⋯O氢键,甲酯基团位于环平面内(O原子偏离平面的距离分别为-0.051(2)和0.151(2)Å)。在晶体中,分子通过相当弱的非经典分子间C—H⋯O氢键聚集在一起,形成围绕反演中心的二聚体单元,以R₂²(8)和R₂²(10)模式形成八元环和十元环体系。