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N-（2-甲酰基苯基）苯磺酰胺

N-(2-Formyl-phen-yl)benzene-sulfonamide.

作者信息

Thenmozhi S, Ranjith S, Subbiahpandi A, Dhayalan V, Mohanakrishnan A K

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 22;65(Pt 9):o2210. doi: 10.1107/S1600536809032681.

DOI:10.1107/S1600536809032681
PMID:21577611
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969910/
Abstract

In the title compound, C(13)H(11)NO(3)S, the two aromatic rings are oriented at an angle of 88.18 (8)°. Intra-molecular N-H⋯O and C-H⋯O hydrogen bonds are observed, each of which generates an S(6) ring motif. In the crystal, mol-ecules are linked into C(7) chains along [010] by inter-molecular C-H⋯O hydrogen bonds. The structure is further stabilized by inter-molecular C-H⋯π inter-actions involving the sulfonyl-bound phenyl ring.

摘要

在标题化合物C₁₃H₁₁NO₃S中，两个芳香环以88.18 (8)°的角度取向。观察到分子内的N-H⋯O和C-H⋯O氢键，每个氢键都形成一个S(6)环模式。在晶体中，分子通过分子间的C-H⋯O氢键沿[010]方向连接成C(7)链。该结构通过涉及磺酰基连接的苯环的分子间C-H⋯π相互作用进一步稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9aa8/2969910/a1a68e86ddf4/e-65-o2210-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9aa8/2969910/d4a7cadc2878/e-65-o2210-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9aa8/2969910/a1a68e86ddf4/e-65-o2210-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9aa8/2969910/d4a7cadc2878/e-65-o2210-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9aa8/2969910/a1a68e86ddf4/e-65-o2210-fig2.jpg

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本文引用的文献

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