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(2R)-2-苯磺酰胺基-2-苯基乙酸:一种新的单斜晶系多晶型物。

(2R)-2-Benzene-sulfonamido-2-phenyl-ethanoic acid: a new monoclinic polymorph.

作者信息

Khan Islam Ullah, Sharif Shahzad, Arshad Muhammad Nadeem, Idrees Muhammad

机构信息

Materials Chemistry Laboratory, Department of Chemistry, GC University, Lahore, Pakistan.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Sep 12;65(Pt 10):o2436. doi: 10.1107/S160053680903606X.

Abstract

In the title compound, C(14)H(13)NO(4)S, a sulfonamide derivative of phenyl glycine, the aromatic rings are inclined at a dihedral angle of 28.03 (12)°. In the crystal, O-H⋯O hydrogen bonds link the molecules into chains propagating in [100] and a weak C-H⋯O interaction cross-links the chains in the c-axis direction. In the previously published polymorph, the dihedral angle between the aromatic rings is 45.52 (18)° and the structure is stabilized by three different types of ring motif.

摘要

在标题化合物C₁₄H₁₃NO₄S(一种苯基甘氨酸的磺酰胺衍生物)中,芳环以28.03 (12)°的二面角倾斜。在晶体中,O—H⋯O氢键将分子连接成沿[100]方向延伸的链,并且一个弱的C—H⋯O相互作用在c轴方向上使这些链交联。在先前发表的多晶型物中,芳环之间的二面角为45.52 (18)°,并且结构由三种不同类型的环基序稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6d3e/2970412/4f1c01285048/e-65-o2436-fig1.jpg

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