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N,N'-双(2-喹啉甲酰基)肼

N,N'-Bis(2-quinolylcarbon-yl)hydrazine.

作者信息

Cheng Hui-Min, Chen Lang, Lu Wei, Shen Xuan, Zhu Dun-Ru

机构信息

College of Chemistry and Chemical Engineering, State Key Laboratory of Materials-oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Sep 26;65(Pt 10):o2526. doi: 10.1107/S1600536809037842.

Abstract

The title compound, C(20)H(14)N(4)O(2), crystallizes in the ortho-rhom-bic system with a crystallographic twofold axis through the N-N bond. The mol-ecule is non-planar and the dihedral angle between two amide groups is 74.9 (2)°. An intra-molecular N-H⋯N hydrogen bond is present. In the crystal, the mol-ecules are packed in chains running along the c axis through inter-molecular N-H⋯O hydrogen bonds. These chains are further stabilized by inter-molecular C-H⋯O hydrogen bonds and C-H⋯π inter-actions leading to the formation of a three-dimensional network.

摘要

标题化合物C(20)H(14)N(4)O(2)以正交晶系结晶,通过N-N键存在一个晶体学二重轴。分子是非平面的,两个酰胺基团之间的二面角为74.9 (2)°。存在分子内N-H⋯N氢键。在晶体中,分子通过分子间N-H⋯O氢键沿c轴堆积成链。这些链通过分子间C-H⋯O氢键和C-H⋯π相互作用进一步稳定,导致形成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec15/2970370/d3d5740e1b80/e-65-o2526-fig1.jpg

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