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13-[4,5-双（甲基硫烷基）-1,3-二硫醇-2-亚基]-6-氧杂-3,9,12,14-四硫杂双环-[9.3.0]十四碳-1(11)-烯

13-[4,5-Bis(methyl-sulfan-yl)-1,3-dithiol-2-yl-idene]-6-oxa-3,9,12,14-tetra-thia-bicyclo-[9.3.0]tetra-dec-1(11)-ene.

作者信息

Hou Rui-Bin, Li Bao, Che Tie, Yin Bing-Zhu, Wu Li-Xin

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Sep 26;65(Pt 10):o2538. doi: 10.1107/S1600536809037301.

DOI:10.1107/S1600536809037301
PMID:21577982
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2970471/
Abstract

In the title mol-ecule, C(14)H(18)OS(8), one O atom, two S atoms and six C atoms form an 11-membered ring with a chair-like conformation; the planes of the two five-membered rings connected by a carbon-carbon double bond form a dihedral angle of 29.97 (11)°. In the crystal, pairs of weak inter-molecular C-H⋯S hydrogen bonds link two mol-ecules into inversion dimers.

摘要

在标题分子C(14)H(18)OS(8)中，一个氧原子、两个硫原子和六个碳原子形成一个具有椅式构象的11元环；由碳 - 碳双键连接的两个五元环的平面形成29.97 (11)°的二面角。在晶体中，成对的弱分子间C - H⋯S氢键将两个分子连接成反演二聚体。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6d68/2970471/70e866e3516e/e-65-o2538-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6d68/2970471/70e866e3516e/e-65-o2538-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6d68/2970471/70e866e3516e/e-65-o2538-fig1.jpg

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