六水合钴（II）双-{[N-（4-甲氧基-2-氧化苯亚甲基）甘氨酰甘氨酸根合]铜（II）}六水合物
Hexaaqua-cobalt(II) bis-{[N-(4-meth-oxy-2-oxidobenzyl-idene)glycyl-glycinato]copper(II)} hexa-hydrate.
作者信息
Yao Gan-Bing, Jiang Jia-Xun, Yuan Li-Min, Ren Xiao-Ming
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 7;65(Pt 11):m1316. doi: 10.1107/S1600536809040045.
Abstract
In the crystal structure of the title compound, [Co(H(2)O)(6)]Cu(C(12)H(11)N(2)O(5))·6H(2)O, the Co(II) atom is located on an inversion center and coordinated by six water mol-ecules in a slightly distorted octa-hedral geometry. The Cu(II) atom is chelated by the Schiff base ligand in a distorted CuN(2)O(2) square-planar geometry. An extensive O-H⋯O hydrogen-bonding network is present in the crystal structure.
摘要
在标题化合物[Co(H₂O)₆][Cu(C₁₂H₁₁N₂O₅)]₂·6H₂O的晶体结构中，Co(II)原子位于一个对称中心上，由六个水分子以稍有畸变的八面体几何构型配位。Cu(II)原子由席夫碱配体以畸变的CuN₂O₂平面正方形几何构型螯合。晶体结构中存在广泛的O—H⋯O氢键网络。
Zotero 插件