• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

[2-(3,5-二甲基-1H-吡唑-1-基-κN)-1,10-菲咯啉-κN,N']双(硫氰酸根-κN)镉(II)

[2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN)-1,10-phenanthroline-κN,N']bis-(thio-cyanato-κN)cadmium(II).

作者信息

Wang Yu Qing, Meng Lin, Shi Jing Min

机构信息

Department of Chemistry, Shandong Normal University, Jinan 250014, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 7;65(Pt 11):m1317. doi: 10.1107/S1600536809039920.

DOI:10.1107/S1600536809039920
PMID:21578080
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2970966/
Abstract

In the title complex, [Cd(NCS)(2)(C(17)H(14)N(4))], the Cd(II) ion is in a distorted trigonal-bipyramidal CdN(5) coordination geometry. In the crystal structure, there is a π-π stacking inter-action involving a pyrazole ring and a symmetry-related pyridine ring with a centroid-centroid distance of 3.578 (3) Å.

摘要

在标题配合物[Cd(NCS)₂(C₁₇H₁₄N₄)]中，Cd(II)离子处于扭曲的三角双锥CdN₅配位几何构型中。在晶体结构中，存在一种π-π堆积相互作用，涉及一个吡唑环和一个对称相关的吡啶环，其质心间距为3.578 (3) Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa12/2970966/d7aeb6269cd6/e-65-m1317-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa12/2970966/d7aeb6269cd6/e-65-m1317-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa12/2970966/d7aeb6269cd6/e-65-m1317-fig1.jpg

相似文献

1
[2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN)-1,10-phenanthroline-κN,N']bis-(thio-cyanato-κN)cadmium(II).[2-(3,5-二甲基-1H-吡唑-1-基-κN)-1,10-菲咯啉-κN,N']双(硫氰酸根-κN)镉(II)
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 7;65(Pt 11):m1317. doi: 10.1107/S1600536809039920.
2
[2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN)-1,10-phenanthroline-κN,N']bis-(thio-cyanato-κN)cadmium(II).[2,9-双(3,5-二甲基-1H-吡唑-1-基-κN)-1,10-菲咯啉-κN,N']双(硫氰酸根-κN)镉(II)
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 11;67(Pt 1):m68. doi: 10.1107/S1600536810051275.
3
Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN)-1,10-phenanthroline-κN,N']cadmium(II).二氯[2-(3,5-二甲基-1H-吡唑-1-基-κN)-1,10-菲咯啉-κN,N']镉(II)
Acta Crystallogr Sect E Struct Rep Online. 2010 May 15;66(Pt 6):m663. doi: 10.1107/S1600536810016910.
4
[2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN)-1,10-phenanthroline-κN,N'](methanol-κO)(nitrito-κO,O')cadmium(II) perchlorate.高氯酸[2,9-双(3,5-二甲基-1H-吡唑-1-基-κN)-1,10-菲咯啉-κN,N'](甲醇-κO)(亚硝酸根-κO,O')镉(II)
Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 12;67(Pt 3):m330. doi: 10.1107/S1600536811003813.
5
Bis[2-(1H-1,2,4-triazol-1-yl-κN)-1,10-phenanthroline-κN,N']cadmium(II) bis-(perchlorate).双[2-(1H-1,2,4-三唑-1-基-κN)-1,10-菲咯啉-κN,N']镉(II) 双(高氯酸盐)
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 3;65(Pt 11):m1280. doi: 10.1107/S1600536809038768.
6
Bis(2-chloro-1,10-phenanthroline-κN,N')(thio-cyanato-κN)zinc (2-chloro-1,10-phenanthroline-κN,N')tris-(thio-cyanato-κN)zincate.
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m202. doi: 10.1107/S1600536812002280. Epub 2012 Jan 25.
7
[2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN)-1,10-phenanthroline-κN,N']bis-(nitrito-κO,O')cadmium(II).[2-(3,5-二甲基-1H-吡唑-1-基-κN)-1,10-菲咯啉-κN,N']双(亚硝酸根-κO,O')镉(II)
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 3;66(Pt 8):m878. doi: 10.1107/S160053681002550X.
8
(2-Meth-oxy-1,10-phenanthroline-κN,N')bis-(thio-cyanato-κN)zinc(II).（2-甲氧基-1,10-菲咯啉-κN,N'）双（硫氰酸根-κN）锌（II）
Acta Crystallogr Sect E Struct Rep Online. 2008 May 3;64(Pt 6):m770. doi: 10.1107/S1600536808011793.
9
Di-μ-thio-cyanato-κN:S;κS:N-bis-[bis-(2-methyl-1H-benzimidazole-κN)(thio-cyanato-κN)cadmium(II)].二-μ-硫氰酸根合-κN:S;κS:N-双-[双-(2-甲基-1H-苯并咪唑-κN)(硫氰酸根合-κN)镉(II)]
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 23;66(Pt 11):m1464. doi: 10.1107/S1600536810042443.
10
(2,9-Dieth-oxy-1,10-phenanthroline-κN,N')bis-(thio-cyanato-κN)cobalt(II).（2,9 - 二乙氧基 - 1,10 - 菲咯啉 - κN,N'）双（硫氰酸根 - κN）钴（II）
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 31;64(Pt 11):m1484. doi: 10.1107/S160053680803496X.

引用本文的文献

1
[2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN)-1,10-phenanthroline-κN,N']bis-(nitrito-κO,O')cadmium(II).[2-(3,5-二甲基-1H-吡唑-1-基-κN)-1,10-菲咯啉-κN,N']双(亚硝酸根-κO,O')镉(II)
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 3;66(Pt 8):m878. doi: 10.1107/S160053681002550X.
2
Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN)-1,10-phenanthroline-κN,N']cadmium(II).二氯[2-(3,5-二甲基-1H-吡唑-1-基-κN)-1,10-菲咯啉-κN,N']镉(II)
Acta Crystallogr Sect E Struct Rep Online. 2010 May 15;66(Pt 6):m663. doi: 10.1107/S1600536810016910.
3
[2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN)-1,10-phenanthroline-κN,N']bis-(thio-cyanato-κN)cadmium(II).

本文引用的文献

1
Bis[mu-1-(1,10-phenanthrolin-2-yl)-2-pyridone]bis{aqua[1-(1,10-phenanthrolin-2-yl)-2-pyridone]cadmium(II)} tetrakis(perchlorate).双[μ-1-(1,10-菲咯啉-2-基)-2-吡啶酮]双{水合[1-(1,10-菲咯啉-2-基)-2-吡啶酮]镉(II)}高氯酸盐。
Acta Crystallogr C. 2008 Jan;64(Pt 1):m58-60. doi: 10.1107/S0108270107063718. Epub 2007 Dec 14.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
[2,9-双(3,5-二甲基-1H-吡唑-1-基-κN)-1,10-菲咯啉-κN,N']双(硫氰酸根-κN)镉(II)
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 11;67(Pt 1):m68. doi: 10.1107/S1600536810051275.