Qi Xu, Shao Ming, Li Chen-Xin
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 10;65(Pt 11):m1334. doi: 10.1107/S1600536809040185.
The title compound, {[Co(C(14)H(16)N(5)O(3))(2)]·2H(2)O}(n) or [Co(ppa)(2)]·2H(2)O}(n), where ppa denotes the 8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydro-pyrido[2,3-d]pyrimidine-6-carb-ox-yl-ate anion, was synthesized under hydro-thermal conditions. The Co(II) atom (site symmetry ) exhibits a distorted trans-CoN(2)O(4) octa-hedral geometry defined by two monodentate N-bonded and two bidentate O,O'-bonded ppa anions. The extended two-dimensional structure is a square grid, which is consolidated by N-H⋯O hydrogen bonds. The disordered uncoordinated water mol-ecules occupy cavities within the grid.
标题化合物{[Co(C₁₄H₁₆N₅O₃)₂]·2H₂O}ₙ或[Co(ppa)₂]·2H₂O}ₙ,其中ppa表示8 - 乙基 - 5 - 氧代 - 2 - (哌嗪 - 1 - 基)-5,8 - 二氢吡啶并[2,3 - d]嘧啶 - 6 - 羧酸根阴离子,是在水热条件下合成的。Co(II)原子(位点对称性)呈现出由两个单齿N键合和两个双齿O,O'-键合的ppa阴离子定义的扭曲反式CoN₂O₄八面体几何构型。扩展的二维结构是一个方格网,通过N - H⋯O氢键得以巩固。无序的未配位水分子占据网格内的空穴。