Yang Yun-Xia, Li Qi, Ng Seik Weng
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 3;65(Pt 11):o2602. doi: 10.1107/S1600536809039099.
In the crystal structure of the title hydrated salt, 2C(4)H(12)N(+)·C(2)O(4) (2-)·H(2)O, the two independent cations, the anion and the water mol-ecule all lie on special positions of m site symmetry. In both cations, the mirror plane passes through the nitrogen atom and two methyl groups; in the anion, the mirror plane passes through two carbon and two oxygen atoms. The anions and water mol-ecules inter-act by O-H⋯O hydrogen bonding, forming a chain running along the b axis.
在标题水合盐2C(4)H(12)N(+)·C(2)O(4)(2-)·H(2)O的晶体结构中,两个独立的阳离子、阴离子和水分子均位于m位点对称的特殊位置上。在两个阳离子中,镜面均穿过氮原子和两个甲基;在阴离子中,镜面穿过两个碳原子和两个氧原子。阴离子和水分子通过O-H⋯O氢键相互作用,形成一条沿b轴延伸的链。