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三（1-萘基）胂氯仿溶剂化物

Tris(1-naphth-yl)arsine chloro-form solvate.

作者信息

Shawkataly Omar Bin, Khan Imthyaz Ahmed, Yeap Chin Sing, Fun Hoong-Kun

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 17;65(Pt 11):o2772-3. doi: 10.1107/S1600536809041646.

DOI:10.1107/S1600536809041646
PMID:21578366
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2971302/
Abstract

In the title compound, C(30)H(21)As·CHCl(3), the dihedral angles between the three naphthalene ring systems [r.m.s. deviations = 0.007, 0.009 and 0.020 Å] are 72.54 (4), 88.05 (4) and 83.36 (4)°. In the crystal, the mol-ecules are stacked down the a axis being consolidated by C-H⋯π and π-π inter-actions [centroid to centroid distance = 3.7839 (7) Å].

摘要

在标题化合物C(30)H(21)As·CHCl(3)中，三个萘环系统之间的二面角[r.m.s.偏差分别为0.007、0.009和0.020 Å]为72.54 (4)°、88.05 (4)°和83.36 (4)°。在晶体中，分子沿a轴堆积，通过C-H⋯π和π-π相互作用得以稳固[质心到质心距离 = 3.7839 (7) Å]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c373/2971302/151810ea0ecd/e-65-o2772-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c373/2971302/2f5a61759fa8/e-65-o2772-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c373/2971302/151810ea0ecd/e-65-o2772-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c373/2971302/2f5a61759fa8/e-65-o2772-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c373/2971302/151810ea0ecd/e-65-o2772-fig2.jpg

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