Suppr超能文献

三(1-萘基)胂氯仿溶剂化物

Tris(1-naphth-yl)arsine chloro-form solvate.

作者信息

Shawkataly Omar Bin, Khan Imthyaz Ahmed, Yeap Chin Sing, Fun Hoong-Kun

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 17;65(Pt 11):o2772-3. doi: 10.1107/S1600536809041646.

Abstract

In the title compound, C(30)H(21)As·CHCl(3), the dihedral angles between the three naphthalene ring systems [r.m.s. deviations = 0.007, 0.009 and 0.020 Å] are 72.54 (4), 88.05 (4) and 83.36 (4)°. In the crystal, the mol-ecules are stacked down the a axis being consolidated by C-H⋯π and π-π inter-actions [centroid to centroid distance = 3.7839 (7) Å].

摘要

在标题化合物C(30)H(21)As·CHCl(3)中,三个萘环系统之间的二面角[r.m.s.偏差分别为0.007、0.009和0.020 Å]为72.54 (4)°、88.05 (4)°和83.36 (4)°。在晶体中,分子沿a轴堆积,通过C-H⋯π和π-π相互作用得以稳固[质心到质心距离 = 3.7839 (7) Å]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c373/2971302/2f5a61759fa8/e-65-o2772-fig1.jpg

相似文献

1
Tris(1-naphth-yl)arsine chloro-form solvate.三(1-萘基)胂氯仿溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 17;65(Pt 11):o2772-3. doi: 10.1107/S1600536809041646.
4
(E)-1-Methyl-4-[2-(1-naphth-yl)vin-yl]pyridinium 4-chloro-benzene-sulfonate.
Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 18;65(Pt 12):o3115-6. doi: 10.1107/S1600536809047734.
7
3-(4-Chloro-phen-yl)-1-(4-nitro-phen-yl)benzo[f]quinoline.3-(4-氯苯基)-1-(4-硝基苯基)苯并[f]喹啉
Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 12;65(Pt 9):o2137. doi: 10.1107/S1600536809031122.
10
3-(3-Chloro-phenyl-sulfin-yl)-2,5,7-trimethyl-1-benzofuran.3-(3-氯-苯基-亚磺酰基)-2,5,7-三甲基-1-苯并呋喃
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):o943. doi: 10.1107/S1600536812008537. Epub 2012 Mar 3.

本文引用的文献

2
1,6-Bis(diphenyl-arsino)hexa-ne.
Acta Crystallogr Sect E Struct Rep Online. 2009 Sep 30;65(Pt 10):o2591-2. doi: 10.1107/S1600536809036757.
3
Structure validation in chemical crystallography.化学晶体学中的结构验证
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
4
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验