Suppr超能文献

(E)-N-[2-(苄基亚氨基甲基)苯基]-2,6-二异丙基苯胺

(E)-N-[2-(Benzyl-iminometh-yl)phen-yl]-2,6-diisopropyl-aniline.

作者信息

Liu Yi-Chang, Lin Chia-Her, Chen Hsiao-Li, Ko Bao-Tsan

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 17;65(Pt 11):o2791. doi: 10.1107/S1600536809042202.

Abstract

The mol-ecular conformation of the title compound, C(26)H(30)N(2), is reinforced by an intra-molecular N-H⋯N hydrogen bond, resulting in an almost planar [mean deviation of 0.023 (2) Å] S(6) ring. The dihedral angles between the central benzene ring and the terminal unsubstituted and substituted aromatic rings are 64.45 (9) and 89.40 (8)°, respectively.

摘要

标题化合物C(26)H(30)N(2)的分子构象通过分子内N-H⋯N氢键得到加强,形成了一个几乎平面的[平均偏差为0.023 (2) Å] S(6)环。中心苯环与末端未取代和取代的芳香环之间的二面角分别为64.45 (9)°和89.40 (8)°。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0c41/2970998/1c00f90d2f1f/e-65-o2791-fig1.jpg

相似文献

1
(E)-N-[2-(Benzyl-iminometh-yl)phen-yl]-2,6-diisopropyl-aniline.
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 17;65(Pt 11):o2791. doi: 10.1107/S1600536809042202.
2
(E)-N-{2-[1-(Benzyl-imino)eth-yl]phen-yl}benzamide.
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 3;66(Pt 4):o745. doi: 10.1107/S1600536810007610.
3
{5-Chloro-2-[(2-hy-droxy-benzyl-idene)amino]-phen-yl}(phen-yl)methanone.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):o3442-3. doi: 10.1107/S1600536811048690. Epub 2011 Nov 25.
4
4-{2-[2-(4-Chloro-benzyl-idene)hydrazinyl-idene]-3,6-dihydro-2H-1,3,4-thia-diazin-5-yl}-3-(4-meth-oxy-phen-yl)sydnone.
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):o1175-6. doi: 10.1107/S1600536811013900. Epub 2011 Apr 22.
6
1-[2-(2,4-Dinitro-benzyl-ideneamino)phen-yl]-3-phenyl-thio-urea.
Acta Crystallogr Sect E Struct Rep Online. 2009 Sep 12;65(Pt 10):o2447. doi: 10.1107/S1600536809035880.
7
N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)-2-[4-(methyl-sulfan-yl)phen-yl]acetamide.
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):o2677. doi: 10.1107/S1600536812034605. Epub 2012 Aug 11.
8
(E)-N'-(2-Hydroxy-benzyl-idene)-2-(4-isobutyl-phen-yl)propanohydrazide.
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 4;66(Pt 1):o24. doi: 10.1107/S1600536809050971.
9
11-[(E)-4-Bromo-benzyl-idene]-8-(4-bromo-phen-yl)-14-hy-droxy-3,13-diaza-hepta-cyclo-[13.7.1.1.0.0.0.0]tetra-cosa-1(22),15,17,19(23),20-pentaen-10-one.
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 23;66(Pt 11):o2926-7. doi: 10.1107/S1600536810042091.
10
1-(2,3-Dimeth-oxy-benzyl-idene)-2-(2,4-dinitro-phen-yl)hydrazine.
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):o1169. doi: 10.1107/S1600536811013894. Epub 2011 Apr 16.

引用本文的文献

1
(E)-N-{2-[1-(Benzyl-imino)eth-yl]phen-yl}benzamide.
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 3;66(Pt 4):o745. doi: 10.1107/S1600536810007610.

本文引用的文献

1
Bimetallic anilido-aldimine Al or Zn complexes for efficient ring-opening polymerization of epsilon-caprolactone.
Dalton Trans. 2008 Jun 28(24):3199-206. doi: 10.1039/b719017d. Epub 2008 Apr 17.
2
A short history of SHELX.
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Bimetallic anilido-aldimine zinc complexes for epoxide/CO2 copolymerization.
J Am Chem Soc. 2005 Mar 9;127(9):3031-7. doi: 10.1021/ja0435135.

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验