四（8-喹啉醇根-κN，O）铪（IV）二甲基甲酰胺溶剂合物一水合物
Tetra-kis(8-quinolinolato-κN,O)hafnium(IV) dimethyl-formamide solvate monohydrate.
作者信息
Viljoen Johannes A, Visser Hendrik G, Roodt Andreas
机构信息
Department of Chemistry, University of the Free State, PO Box 339, Bloemfontein 9300, South Africa.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 30;66(Pt 5):m603-4. doi: 10.1107/S1600536810014960.
In the title compound, [Hf(C(9)H(6)NO)]·C(3)H(7)NO·H(2)O, the hafnium(IV) atom is coordinated by four 8-quinolinolate (Ox) ligands, forming a slightly distorted square-anti-prismatic coordination polyhedron. The crystal packing is controlled by O-H⋯O and C-H⋯O hydrogen-bonding inter-actions and π-π inter-actions between quinoline ligands of neighbouring mol-ecules. The inter-planar distances vary between 3.150 (1) and 3.251 (2) Å, while centroid-centroid distances vary from 3.589 (1) to 4.1531 (1) Å.
在标题化合物[Hf(C₉H₆NO)]·C₃H₇NO·H₂O中，铪(IV)原子由四个8-喹啉醇盐（Ox）配体配位，形成一个稍有畸变的四方反棱柱配位多面体。晶体堆积由O—H⋯O和C—H⋯O氢键相互作用以及相邻分子喹啉配体之间的π-π相互作用控制。平面间距离在3.150 (1) Å至3.251 (2) Å之间变化，而质心-质心距离在3.589 (1) Å至4.1531 (1) Å之间变化。
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