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17,18 - 二溴 - 8 - 甲基 - 4,12 - 二对甲苯磺酰基 - 3,4,5,6,7,8,9,10,11,12,13,14 - 十二氢 - 2H - 苯并[b][1,4,7,11,15]二氧杂三氮杂环十七碳烯

17,18-Dibromo-8-methyl-4,12-ditosyl-3,4,5,6,7,8,9,10,11,12,13,14-dodeca-hydro-2H-benzo[b][1,4,7,11,15]dioxatriaza-cyclo-hepta-decine.

作者信息

Keleşoğlu Zeynep, Celenk Kaya Elif, Kantekin Halit, Büyükgüngör Orhan

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 14;66(Pt 5):o1082. doi: 10.1107/S1600536810013097.

DOI:10.1107/S1600536810013097
PMID:21579136
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2979080/
Abstract

In the title compound, C(31)H(39)Br(2)N(3)O(6)S(2), a 17-membered aza-macrocyclic ligand containing two ether O and three aza N atoms, the three pendant aromatic rings form an 'E' shape. The dihedral angles between the central benzene ring and the side ones are 17.8 (3) and 7.4 (3)°, and the dihedral angle between the tosyl rings is 10.6 (3)°. The methyl group is disordered over two orientations, with occupancies of 0.52 (15) and 0.48 (15).

摘要

在标题化合物C(31)H(39)Br(2)N(3)O(6)S(2)中，一个含有两个醚氧原子和三个氮杂原子的17元氮杂大环配体，三个悬挂的芳香环形成一个“E”形。中心苯环与侧苯环之间的二面角分别为17.8 (3)°和7.4 (3)°，对甲苯磺酰环之间的二面角为10.6 (3)°。甲基在两个取向上无序，占有率分别为0.52 (15)和0.48 (15)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f16/2979080/0f2308fc8f43/e-66-o1082-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f16/2979080/0f2308fc8f43/e-66-o1082-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f16/2979080/0f2308fc8f43/e-66-o1082-fig1.jpg

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