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N-苄基-2-(2-溴苯基)-2-(2-硝基苯氧基)乙酰胺

N-Benzyl-2-(2-bromo-phen-yl)-2-(2-nitro-phen-oxy)acetamide.

作者信息

Li Huo Ming, Wu Jin-Long

机构信息

Laboratory of Asymmetric Catalysis and Synthesis, Department of Chemistry, Zhejiang University, Hangzhou, Zhejiang 310027, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 May 8;66(Pt 6):o1274. doi: 10.1107/S1600536810014996.

DOI:10.1107/S1600536810014996
PMID:21579375
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2979402/
Abstract

The title compound, C(21)H(17)BrN(2)O(4), a 2-phen-oxy-2-phenyl-acetamide derivative, exhibits a stereogenic center but crystallizes as a racemate as indicated by the centrosymmetric space group. In the mol-ecular structure, the nitro-substituted benzene ring is coplanar [dihedral angle = 12.9 (1)°] with the plane formed by H-N-C(=O)-C=O due to intra-molecular N-H⋯O hydrogen-bond inter-actions.

摘要

标题化合物C(21)H(17)BrN(2)O(4)，一种2-苯氧基-2-苯基乙酰胺衍生物，具有一个手性中心，但如中心对称空间群所示，它以外消旋体形式结晶。在分子结构中，由于分子内N-H⋯O氢键相互作用，硝基取代的苯环与由H-N-C(=O)-C=O形成的平面共面[二面角 = 12.9 (1)°]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/95a1/2979402/5246d6c05d15/e-66-o1274-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/95a1/2979402/5246d6c05d15/e-66-o1274-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/95a1/2979402/5246d6c05d15/e-66-o1274-fig1.jpg

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