Yang Bao-He, Niu Jun-Long
Acta Crystallogr Sect E Struct Rep Online. 2010 May 8;66(Pt 6):o1300. doi: 10.1107/S1600536810016156.
In the title Schiff base compound, C(12)H(15)N(3)O(2), obtained from a condensation reaction of cyclo-hexa-none and 2-nitro-phenyl-hydrazine, the phenyl-hydrazone group is planar, the largest deviation from the mean plane being 0.0252 (12) Å, and the nitro fragment is twisted slightly with respect to the mean plane, making a dihedral angle of 6.96 (17)°. The cyclo-heaxanone ring displays a chair conformation. An intra-molecular N-H⋯O hydrogen bond helps to stabilize the mol-ecular structure.
在标题席夫碱化合物C(12)H(15)N(3)O(2)中,它由环己酮与2-硝基苯肼的缩合反应制得,苯腙基团呈平面状,与平均平面的最大偏差为0.0252 (12) Å,硝基片段相对于平均平面略有扭曲,二面角为6.96 (17)°。环己酮环呈椅式构象。分子内N-H⋯O氢键有助于稳定分子结构。