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（E）-1-（3-甲氧基苯基）乙酮4-硝基苯腙

(E)-1-(3-Methoxy-phen-yl)ethanone 4-nitro-phenyl-hydrazone.

作者信息

Fan Zheng, Shan Shang, Wang Shan-Heng, Wang Wen-Long

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 25;64(Pt 7):o1341. doi: 10.1107/S1600536808018618.

DOI:10.1107/S1600536808018618
PMID:21202963
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2961743/
Abstract

Crystals of the title compound, C(15)H(15)N(3)O(3), were obtained from a condensation reaction of 4-nitro-phenyl-hydrazine and 3-methoxy-acetophenone. In the crystal structure, the methoxy-phenyl ring is twisted slightly with respect to the nitro-phenyl-hydrazine plane, making a dihedral angle of 14.81 (8)°. The nitro and meth-oxy groups are each coplanar with the attached benzene rings. The nitro-phenyl and methoxy-phenyl groups are located on opposite sides of the C=N double bond, indicating an E configuration of the mol-ecule. Adjacent mol-ecules are linked together via N-H⋯O hydrogen bonding, forming chains along the [101] direction.

摘要

标题化合物C(15)H(15)N(3)O(3)的晶体是通过4-硝基苯肼与3-甲氧基苯乙酮的缩合反应得到的。在晶体结构中，甲氧基苯环相对于硝基苯肼平面略有扭曲，二面角为14.81 (8)°。硝基和甲氧基各自与相连的苯环共面。硝基苯基和甲氧基苯基位于C=N双键的两侧，表明该分子具有E构型。相邻分子通过N-H⋯O氢键连接在一起，沿[101]方向形成链状结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ad0a/2961743/6e2bd649b5c2/e-64-o1341-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ad0a/2961743/b0702f0a45fb/e-64-o1341-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ad0a/2961743/6e2bd649b5c2/e-64-o1341-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ad0a/2961743/b0702f0a45fb/e-64-o1341-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ad0a/2961743/6e2bd649b5c2/e-64-o1341-fig2.jpg

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