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2-[2-(2,6-二氯苯胺基)苯基]-N'-(4-丙基-环己叉基)乙酰肼

2-[2-(2,6-Dichloro-anilino)phen-yl]-N'-(4-propyl-cyclo-hexyl-idene)acetohydrazide.

作者信息

Akkurt Mehmet, Nassozi Mebble, Capan Gültaze, Kocabalkanlı Ayşe, Celik Ismail, Büyükgüngör Orhan

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 9;66(Pt 2):o256-7. doi: 10.1107/S1600536809054695.

DOI:10.1107/S1600536809054695
PMID:21579699
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2979672/
Abstract

The asymmetric unit of the title compound, C(23)H(27)Cl(2)N(3)O, contains two crystallographically independent mol-ecules in which the dihedral angles between the benzene rings are 70.1 (3) and 63.8 (3)°. In each mol-ecule an intra-molecular N-H⋯O hydrogen bond generates an S(7) ring. The atoms of the propyl grouping of one mol-ecule are disordered over two orientations with occupancies of 0.666 (6) and 0.334 (6). The crystal structure is stabilized by N-H⋯O and C-H⋯O hydrogen-bonding inter-actions.

摘要

标题化合物C(23)H(27)Cl(2)N(3)O的不对称单元包含两个晶体学独立分子，其中苯环之间的二面角分别为70.1 (3)°和63.8 (3)°。在每个分子中，分子内N-H⋯O氢键形成一个S(7)环。一个分子中丙基基团的原子在两个取向上无序，占有率分别为0.666 (6)和0.334 (6)。晶体结构通过N-H⋯O和C-H⋯O氢键相互作用得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/565e/2979672/590bdcf46fc8/e-66-0o256-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/565e/2979672/570944047ddf/e-66-0o256-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/565e/2979672/590bdcf46fc8/e-66-0o256-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/565e/2979672/570944047ddf/e-66-0o256-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/565e/2979672/590bdcf46fc8/e-66-0o256-fig2.jpg

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