白钨矿型NaDy(WO₄)₂
Scheelite-type NaDy(WO(4))(2).
作者信息
Zhao Dan, Li Feifei, Cheng Wendan, Zhang Hao
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 12;66(Pt 1):i2. doi: 10.1107/S1600536809052271.
Abstract
The title compound sodium dysprosium(III) bis-[tungs-tate(VI)], NaDy(WO(4))(2), has been synthesized under high temperature solution growth (HTSG) conditions in air. The compound crystallizes with the scheelite structure and is composed of isolated WO(4) tetra-hedra ( symmetry) with one set of bond lengths and distorted [(Na/Dy)O(8)] dodeca-hedra ( symmetry; occupancy ratio Na:Dy = 1:1) with two sets of bond lengths.
摘要
标题化合物二水合钨酸镝(III)钠，NaDy(WO₄)₂，是在空气中高温溶液生长（HTSG）条件下合成的。该化合物以白钨矿结构结晶，由具有一组键长的孤立WO₄四面体（对称）和具有两组键长的扭曲[(Na/Dy)O₈]十二面体（对称；Na:Dy占有率比 = 1:1）组成。
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