一水合硝酸铜（II）-[4-氯-2-（2-吡啶基甲基亚氨基甲基）苯酚盐]水合物
Aqua-[4-chloro-2-(2-pyridylmethyl-imino-meth-yl)phenolato]copper(II) nitrate monohydrate.
作者信息
Liang Qing, Chen Xiaodan, Zhang Huaihong, Zou Zhihong
机构信息
Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 12;66(Pt 1):m40. doi: 10.1107/S1600536809052350.
In the title mononuclear complex, [Cu(C(13)H(10)ClN(2)O)(H(2)O)]-NO(3)·H(2)O, the Cu(II) atom is four-coordinated by two N atoms and one O atom of the tridentate Schiff base ligand and one O atom from the coordinated water mol-ecule in a slightly distorted square-planar configuration. The nitrate ion inter-acts with the copper center [Cu1⋯O3 = 2.579 (4) Å]. In the crystal, the cations, anions and water mol-ecules are linked by O-H⋯O and O-H⋯N hydrogen bonds.
在标题单核配合物[Cu(C₁₃H₁₀ClN₂O)(H₂O)]-NO₃·H₂O中，Cu(II)原子由三齿席夫碱配体的两个N原子、一个O原子以及配位水分子的一个O原子以略微扭曲的平面正方形构型进行四配位。硝酸根离子与铜中心相互作用[Cu1⋯O3 = 2.579(4) Å]。在晶体中，阳离子、阴离子和水分子通过O-H⋯O和O-H⋯N氢键相连。
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