Liang Qing, Chen Xiaodan, Zhang Huaihong, Zou Zhihong
Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 12;66(Pt 1):m40. doi: 10.1107/S1600536809052350.
In the title mononuclear complex, [Cu(C(13)H(10)ClN(2)O)(H(2)O)]-NO(3)·H(2)O, the Cu(II) atom is four-coordinated by two N atoms and one O atom of the tridentate Schiff base ligand and one O atom from the coordinated water mol-ecule in a slightly distorted square-planar configuration. The nitrate ion inter-acts with the copper center [Cu1⋯O3 = 2.579 (4) Å]. In the crystal, the cations, anions and water mol-ecules are linked by O-H⋯O and O-H⋯N hydrogen bonds.
在标题单核配合物[Cu(C₁₃H₁₀ClN₂O)(H₂O)]-NO₃·H₂O中，Cu(II)原子由三齿席夫碱配体的两个N原子、一个O原子以及配位水分子的一个O原子以略微扭曲的平面正方形构型进行四配位。硝酸根离子与铜中心相互作用[Cu1⋯O3 = 2.579(4) Å]。在晶体中，阳离子、阴离子和水分子通过O-H⋯O和O-H⋯N氢键相连。
