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Poly[aqua-[μ(2)-cis-1,2-bis-(4-pyrid-yl)ethyl-ene-κN:N'](μ(2)-5-nitro-isophthalato-κO:O',O'')nickel(II)].

作者信息

Fan Zhen-Zhong, Wang Guo-Ping, Li Yu-Sheng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 19;66(Pt 1):m80-1. doi: 10.1107/S1600536809053872.

Abstract

In the title compound, Ni(C(8)H(3)NO(6))(C(12)H(10)N(2))(H(2)O), the Ni(II) atom is octa-hedrally coordinated by two cis N atoms from two different 1,2-bis-(4-pyrid-yl)ethyl-ene (bpe) ligands, two O atoms from one chelating carboxyl group of the 5-nitro-isophthalic acid (nip) ligand, one O atom from another monodentate nip ligand and one O atom from a water mol-ecule, forming a three-dimensional network structure. Inter-molecular O-H⋯O hydrogen bonding stabilizes this arrangement. The asymmetric unit of the structure contains one Ni(II) atom, one water mol-ecule, one nip ligand and two half-mol-ecules of the bpe ligand with an inversion centre at the mid-point of the central C=C bond.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/646a/2980111/9f2b24f1114c/e-66-00m80-fig1.jpg

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