Hexakis(N,N-dimethyl-formamide-κO)cobalt(II) bis-(perchlorate).
作者信息
Eissmann Frank, Böhle Tony, Mertens Florian O R L, Weber Edwin
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Feb 10;66(Pt 3):m279. doi: 10.1107/S160053681000454X.
Abstract
The asymmetric unit of the title complex, Co(DMF)(6)(2) (DMF = N,N-dimethyl-formamide, C(3)H(7)NO), consists of two half complex cations with the Co(2+) metal ions located on centers of inversion and two perchlorate anions. In the crystal packing, each Co(2+) ion is coordinated by six mol-ecules of DMF in a slightly distorted octa-hedral geometry. The crystal structure is mainly stabilized by coordinative, ionic and C-H⋯O hydrogen-bonding inter-actions.
摘要
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