（E）-1-苯基-2-（{5-[(1E)-(2-苯基肼-1-基亚甲基)甲基]-2-噻吩基}亚甲基）肼
(E)-1-Phenyl-2-({5-[(1E)-(2-phenyl-hydrazin-1-yl-idene)meth-yl]-2-thien-yl}methyl-idene)hydrazine.
作者信息
de Lima Geraldo M, Harrison William T A, Tiekink Edward R T, Wardell James L, Wardell Solange M S V
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Feb 3;66(Pt 3):o504-5. doi: 10.1107/S1600536810003302.
The title mol-ecule, C(18)H(16)N(4)S, adopts a U-shape with the aromatic groups lying syn and orientated in the same direction as the thio-phene S atom. The conformation about each of the C=N bonds is E. Overall, the mol-ecule is curved as seen in the dihedral angle of 30.26 (19)° formed between the terminal benzene rings. In the crystal, supra-molecular chains along the c axis are formed by a combination of N-H⋯N hydrogen bonds and N-H⋯π inter-actions.
标题分子C(18)H(16)N(4)S呈U形，芳基位于同侧，且与噻吩S原子方向相同。每个C=N键的构象均为E型。总体而言，从末端苯环之间形成的30.26 (19)°二面角可以看出，该分子呈弯曲状。在晶体中，沿c轴的超分子链由N-H⋯N氢键和N-H⋯π相互作用共同形成。
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