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α-木香酸酐

α-Costic anhydride.

作者信息

Tebbaa Mohamed, Akssira Mohamed, Elhakmaoui Ahmed, El Ammari Lahcen, Benharref Ahmed, Berraho Moha

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Feb 13;66(Pt 3):o589-90. doi: 10.1107/S1600536810005064.

DOI:10.1107/S1600536810005064
PMID:21580353
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2983650/
Abstract

THE TITLE COMPOUND [SYSTEMATIC NAME: 2-(4a,8-dimethyl-1,2,3,4,4a,5,6,8a-octa-hydro-naphthalen-2-yl)acrylic acid anhydride], C(30)H(42)O(3), is a new isocostic anhydride which was synthesized from the aerial part of Inula Viscosa- (L) Aiton [or Dittrichia Viscosa- (L) Greuter]. The mol-ecule adopts an essentially linear shape with two terminal fused-rings bridged by the anhydride group. The external rings have the same conformation (half-chair) while each of the two inner rings has an almost ideal chair conformation. In the crystal, inter-molecular C-H⋯O inter-actions link the mol-ecules into a two-dimensional array in the bc plane.

摘要

标题化合物[系统名称:2-(4a,8-二甲基-1,2,3,4,4a,5,6,8a-八氢萘-2-基)丙烯酸酐],C(30)H(42)O(3),是一种新的异贝壳杉烯酸酐,由粘旋覆花[或粘毛旋覆花,(L)艾顿]的地上部分合成。分子呈基本线性形状,由酸酐基团桥连两个末端稠环。外环具有相同的构象(半椅式),而两个内环中的每一个都具有几乎理想的椅式构象。在晶体中,分子间的C-H⋯O相互作用将分子连接成bc平面中的二维阵列。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/25c3/2983650/a566b35f0f00/e-66-0o589-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/25c3/2983650/b60acbbd10b6/e-66-0o589-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/25c3/2983650/a566b35f0f00/e-66-0o589-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/25c3/2983650/b60acbbd10b6/e-66-0o589-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/25c3/2983650/a566b35f0f00/e-66-0o589-fig2.jpg

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