Chen Junqing, Zha Xiaoming
Acta Crystallogr Sect E Struct Rep Online. 2010 Feb 13;66(Pt 3):o607. doi: 10.1107/S1600536810005167.
The title compound, C(24)H(37)BrO(3), is a tetra-cyclic diterpenoid with a beyerane skeleton, synthesized by esterification of isosteviol. It comprises a fused four-ring system A/B/C/D. Rings A and B have a chair conformation, whereas ring C is an unsymmetrical distorted chair; the remaining five-membered ring D adopts an envelope conformation. The stereochemistry of the A/B and B/C ring junctions are trans, while the C/D junction is cis.
标题化合物C(24)H(37)BrO(3)是一种具有贝壳杉烷骨架的四环二萜类化合物,由异甜菊醇酯化合成。它包含一个稠合四环体系A/B/C/D。环A和环B呈椅式构象,而环C是不对称扭曲椅式;其余的五元环D呈信封式构象。A/B和B/C环连接处的立体化学为反式,而C/D连接处为顺式。