聚[（二甲基甲酰胺）（μ(4)-2,2'-硫代二苯甲酸根）镍（II）]
Poly[(dimethyl-formamide)(μ(4)-2,2'-sulfanediyldibenzoato)nickel(II)].
作者信息
Xie Jiang-Bo
机构信息
College of Materials Science and Engineering, North University of China, Taiyuan, Shanxi, 030051, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 6;66(Pt 4):m368. doi: 10.1107/S1600536810007749.
The title centrosymmetric dinuclear Ni(II) complex, Ni(C(14)H(8)O(4)S)(C(3)H(7)NO), was prepared via reaction of Ni(NO(3))(2)·6H(2)O and thio-salicylic acid, with H(2)O and dimethyl-formamide (DMF) as the mixed solvent. The central Ni(II) ion is five-coordinated by five O atoms from DMF and from the carboxyl-ate groups of the organic ligand. The symmetry-related coordination polyhedra inter-link into centrosymmetric dimeric units and these, in turn, are linked into infinite chains propagating parallel to [100].
标题为中心对称双核镍（II）配合物[Ni(C₁₄H₈O₄S)(C₃H₇NO)]ₙ，通过硝酸镍六水合物（Ni(NO₃)₂·6H₂O）与硫代水杨酸反应制备，以水和二甲基甲酰胺（DMF）作为混合溶剂。中心镍（II）离子由来自DMF和有机配体羧酸根基团的五个氧原子五配位。对称相关的配位多面体相互连接形成中心对称的二聚体单元，这些二聚体单元又连接成平行于[100]方向延伸的无限链。
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