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N-(5-苯基-1H-吡唑-3-基)苯-1,2-二胺

N-(5-Phenyl-1H-pyrazol-3-yl)benzene-1,2-diamine.

作者信息

Doumbia Mohamadou Lamine, Bouhfid Rachid, Essassi El Mokhtar, El Ammari Lahcen

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 17;66(Pt 4):o841. doi: 10.1107/S1600536810009104.

Abstract

In the title compound, C(15)H(14)N(4), the phenyl and pyrazole rings are essentially coplanar, being twisted relative to each other by a dihedral of only 3.68 (11)°. The benzene ring makes a dihedral angle of 64.47 (11)° with the pyrazole ring. The crystal structure is stabilized by two inter-molecular N-H⋯N hydrogen-bonds, which build a two-dimensional network developing parallel to (100). An intra-molecular N-H⋯N hydrogen bond also occurs.

摘要

在标题化合物C₁₅H₁₄N₄中,苯基和吡唑环基本共面,彼此之间的二面角仅为3.68 (11)°。苯环与吡唑环的二面角为64.47 (11)°。晶体结构通过两个分子间N-H⋯N氢键得以稳定,这两个氢键形成了一个平行于(100)扩展的二维网络。分子内也存在N-H⋯N氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cfbb/2983836/8218b1a3f911/e-66-0o841-fig1.jpg

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