Fun Hoong-Kun, Jebas Samuel Robinson, Girish K S, Kalluraya B
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 8;64(Pt 12):o2301-2. doi: 10.1107/S1600536808036088.
In the the title compound, C(27)H(23)ClN(4)O(2), the chloro-phenyl ring forms dihedral angles of 77.70 (9) and 86.65 (9)°, respectively, with the pyrazol-3-one and pyrazole rings. The phenyl rings attached to the pyrazole rings are twisted away from them [dihedral angles 33.80 (9) and 40.34 (10)°]. An intramolecular O-H⋯O hydrogen bond generates an S(8) ring motif. The mol-ecules are linked into chains running along the c axis by N-H⋯N hydrogen bonds, and the chains are cross-linked via C-H⋯O hydrogen bonds and C-H⋯π inter-actions involving the chloro-phenyl ring.
在标题化合物C(27)H(23)ClN(4)O(2)中,氯苯环与吡唑-3-酮环和吡唑环分别形成77.70 (9)°和86.65 (9)°的二面角。连接到吡唑环上的苯环与它们扭转开[二面角为33.80 (9)°和40.34 (10)°]。分子内的O-H⋯O氢键形成一个S(8)环模式。分子通过N-H⋯N氢键连接成沿c轴延伸的链,并且这些链通过C-H⋯O氢键和涉及氯苯环的C-H⋯π相互作用交联。