Lin Jun, Jian Fang-Fang
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 18;64(Pt 11):o2130. doi: 10.1107/S1600536808032996.
The title compound, C(15)H(16)O(6), was prepared by reaction of 2,2-bis-(hydroxy-meth-yl)propane-1,3-diol with 2-furaldehyde in the presence of hydro-chloric acid at room temperature. The asymmetric unit contains two crystallographically independent mol-ecules. In these two mol-ecules, the dihedral angles between the five-membered rings are 56.4 (3) and 56.3 (3)°. The six-membered rings adopt chair conformations. Inter-molecular C-H⋯π inter-actions link the mol-ecules and may be effective in the stabilization of the crystal structure.
标题化合物C(15)H(16)O(6)是由2,2-双(羟甲基)丙烷-1,3-二醇与2-糠醛在室温下于盐酸存在下反应制得的。不对称单元包含两个晶体学独立的分子。在这两个分子中,五元环之间的二面角分别为56.4 (3)°和56.3 (3)°。六元环呈椅式构象。分子间的C-H⋯π相互作用连接这些分子,可能对晶体结构的稳定起有效作用。