Hao Lujiang, Liu Xia
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 8;64(Pt 12):m1498. doi: 10.1107/S1600536808035174.
In the title compound, [Zn(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)(3)]·H(2)O, the Zn(II) cation is hexa-coordinated by a chelating 2,2'-bipyridine ligand, one carboxyl-ate O atom from a 5-nitro-isophthalate dianion and three water mol-ecules in a slightly distorted octa-hedral geometry. The structure contains isolated neutral complexes, in contrast to coordination polymers formed by Mn(II), Co(II) and Cu(II) with the same ligand set. An extensive network of hydrogen bonds is formed between the water mol-ecules and the carboxyl-ate groups.
在标题化合物[Zn(C₈H₃NO₆)(C₁₀H₈N₂)(H₂O)₃]·H₂O中，Zn(II)阳离子由一个螯合的2,2'-联吡啶配体、来自5-硝基间苯二甲酸二阴离子的一个羧酸根O原子以及三个水分子以略微扭曲的八面体几何构型进行六配位。与由Mn(II)、Co(II)和Cu(II)与相同配体形成的配位聚合物不同，该结构包含孤立的中性配合物。水分子与羧酸根基团之间形成了广泛的氢键网络。
