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双[2,4-戊二酮（1-）]双-[4,4,5,5-四甲基-2-（4-吡啶基）-咪唑啉-1-氧基3-氧化物]锰（II）

Bis[2,4-penta-nedionato(1-)]bis-[4,4,5,5-tetra-methyl--2-(4-pyrid-yl)-imidazoline-1-oxyl 3-oxide]manganese(II).

作者信息

Liu Ying, He Qingpeng, Zhang Xianxi, Xue Zechun, Lv Chunyan

机构信息

College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 22;64(Pt 12):m1604. doi: 10.1107/S1600536808038440.

DOI:10.1107/S1600536808038440
PMID:21581201
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2959951/
Abstract

In the title compound, [Mn(C(5)H(7)O(2))(2)(C(12)H(16)N(3)O(2))], the manganese(II) cation (site symmetry ) is hexa-coordinated by four O and two N atoms in a distorted trans-MnN(2)O(4) octa-hedral geometry. The four O atoms belonging to two 2,4-penta-nedionate anions lie in the equatorial plane and the two N atoms occupy the axial coordination sites.

摘要

在标题化合物[Mn(C₅H₇O₂)₂(C₁₂H₁₆N₃O₂)]中，锰(II)阳离子（位点对称性）由四个氧原子和两个氮原子以扭曲的反式-MnN₂O₄八面体几何构型进行六配位。属于两个2,4-戊二酮阴离子的四个氧原子位于赤道平面，两个氮原子占据轴向配位位点。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b5a3/2959951/ff6cec2b7c0c/e-64-m1604-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b5a3/2959951/ff6cec2b7c0c/e-64-m1604-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b5a3/2959951/ff6cec2b7c0c/e-64-m1604-fig1.jpg

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