Agotegaray Mariela A, Quinzani Oscar V, Faccio Ricardo, Goyenola Cecilia, Mombrú Alvaro W
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 26;64(Pt 12):m1612-3. doi: 10.1107/S1600536808038786.
The title compound, [Cu(2)(C(15)H(13)O(3))(4)(C(3)H(7)NO)(2)], is formed by the chelate coordination of four racemic fenoprofenate (fenoprofenate is 2,3-phenoxyphenyl propionate) anions and two dimethyl-formamide mol-ecules to two copper(II) ions, building a paddle-wheel dinuclear mol-ecule. The distorted square-pyramidal coordination of each Cu(II) atom is made up of four O atoms of the four fenoprofenate units and another O atom from a dimethyl-formamide mol-ecule. The two enanti-omeric forms of the fenoprofenate anions are present in the complex, in an optically inactive centrosymmetric arrangement.
标题化合物[Cu₂(C₁₅H₁₃O₃)₄(C₃H₇NO)₂]由四个外消旋非诺洛芬酯（非诺洛芬酯为2,3-苯氧基苯基丙酸酯）阴离子和两个二甲基甲酰胺分子与两个铜(II)离子通过螯合配位形成，构建了一个桨轮状双核分子。每个Cu(II)原子的扭曲四方锥配位由四个非诺洛芬酯单元的四个O原子和来自一个二甲基甲酰胺分子的另一个O原子组成。非诺洛芬酯阴离子的两种对映体形式存在于配合物中，呈光学无活性的中心对称排列。
