（E）-2-（4-氟-亚苄基）环辛酮
(E)-2-(4-Fluoro-benzyl-idene)cyclo-octanone.
作者信息
Zhu Yu-Lin, Xie Min, Zheng Jie, Deng Changquan
机构信息
School of Chemistry and Environment, South China Normal University, Guangzhou 510006, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 22;64(Pt 12):o2417. doi: 10.1107/S1600536808037653.
Abstract
The title compound, C(15)H(17)FO, was prepared directly from the aldol condensation of cyclo-octa-none with 4-fluoro-benz-aldehyde, catalysed by Pd(Ni,Ce) in the presence of trimethyl-silyl chloride. The eight-membered ring adopts a boat-chair conformation.
摘要
标题化合物C(15)H(17)FO是由环辛酮与4-氟苯甲醛在三甲基氯硅烷存在下，以钯（镍、铈）为催化剂直接通过羟醛缩合反应制备得到的。八元环呈船式-椅式构象。
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